Scientists with the University of Chicago have discovered a way to create a material that can be made like a plastic, but conducts electricity more like a metal.
The research, published Oct. 26 in Nature, shows how to make a kind of material in which the molecular fragments are jumbled and disordered, but can still conduct electricity extremely well.
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fundamentally, both of these organic and traditional metallic conductors share a common characteristic. They are made up of straight, closely packed rows of atoms or molecules. This means that electrons can easily flow through the material, much like cars on a highway. In fact, scientists thought a material had to have these straight, orderly rows in order to conduct electricity efficiently.
Then Xie began experimenting with some materials discovered years ago, but largely ignored. He strung nickel atoms like pearls into a string of of molecular beads made of carbon and sulfur, and began testing.
To the scientists’ astonishment, the material easily and strongly conducted electricity. What’s more, it was very stable. “We heated it, chilled it, exposed it to air and humidity, and even dripped acid and base on it, and nothing happened,” said Xie. That is enormously helpful for a device that has to function in the real world.
But to the scientists, the most striking thing was that the molecular structure of the material was disordered. “From a fundamental picture, that should not be able to be a metal,” said Anderson. “There isn’t a solid theory to explain this.”
Xie, Anderson, and their lab worked with other scientists around the university to try to understand how the material can conduct electricity. After tests, simulations, and theoretical work, they think that the material forms layers, like sheets in a lasagna. Even if the sheets rotate sideways, no longer forming a neat lasagna stack, electrons can still move horizontally or vertically—as long as the pieces touch.
The end result is unprecedented for a conductive material. “It’s almost like conductive Play-Doh—you can smush it into place and it conducts electricity,” Anderson said.
The scientists are excited because the discovery suggests a fundamentally new design principle for electronics technology. Conductors are so important that virtually any new development opens up new lines for technology, they explained.
One of the material’s attractive characteristics is new options for processing. For example, metals usually have to be melted in order to be made into the right shape for a chip or device, which limits what you can make with them, since other components of the device have to be able to withstand the heat needed to process these materials.
The new material has no such restriction because it can be made at room temperatures. It can also be used where the need for a device or pieces of the device to withstand heat, acid or alkalinity, or humidity has previously limited engineers’ options to develop new technology.
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More information: John Anderson, Intrinsic glassy-metallic transport in an amorphous coordination polymer, Nature (2022). DOI: 10.1038/s41586-022-05261-4. www.nature.com/articles/s41586-022-05261-4
Source: Scientists discover material that can be made like a plastic but conducts like a metal
Robin Edgar
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